@article{singh2025sulfonated,
author = {Singh, Siddhant and Tami, Jessica L. and Gruich, Cameron and Gatz, Allison J. and Dong, Jason and Nguyen, Bichlien and Smith, Jake and Goldsmith, Bryan R. and McNeil, Anne J. and Kwabi, David G.},
title = {Sulfonated Benzo[c]cinnolines for Alkaline Redox-Flow Batteries},
year = {2025},
month = {June},
abstract = {Aqueous organic redox-flow batteries (RFBs) are promising for grid-scale energy storage, but the development of stable, low-cost electrolytes remains challenging. Herein, azobenzenes were investigated as negative electrolytes because of their low molecular weight and commercial availability. The electrochemical properties and cycling performance of methyl red, an azobenzene dye, were evaluated under alkaline conditions. Analyzing the decomposition products revealed degradation through hydrazo bond cleavage. To attenuate degradation, we tested a more structurally rigid cis-azobenzene with connected aromatic rings, known as benzo[c]cinnoline (BC). The sulfonation of BC enabled a higher aqueous solubility, with the disulfonated product (ds-BC) exhibiting a reduction potential of −0.84 V vs Ag/AgCl. In full cells, ds-BC was paired with ferrocyanide–ferricyanide, producing a 1.11 V battery with a capacity fade rate of 0.77%/day. Density functional theory calculations predicted that reduced BCs exhibit greater thermodynamic stability than azobenzenes. This work introduces benzo[c]cinnoline as a promising molecular scaffold for RFBs.},
url = {http://approjects.co.za/?big=en-us/research/publication/sulfonated-benzoccinnolines-for-alkaline-redox-flow-batteries/},
journal = {ACS Applied Energy Materials},
}